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Question: Answered & Verified by Expert


Arrange $X, Y$ and $Z$ in order of increasing acidic strengths.
ChemistryGeneral Organic ChemistryAIIMSAIIMS 2017
Options:
  • A $X>Z>Y$
  • B $Z < X>Y$
  • C $X>Y>Z$
  • D $Z>X>Y$
Solution:
1858 Upvotes Verified Answer
The correct answer is: $X>Z>Y$
Carboxylic acid is stronger acid than $-\mathrm{NH}_3$, therefore, $X$ is the strongest acid. Since $-\mathrm{COOH}$ has $-I$-effect which decreases with distance, therefore, $-I$-effect is more pronounced on $Z$ than on $Y$. As a result, $Z$ is more acidic than $Y$. Thus, overall order of decreasing acidic strength is $X>Z>Y$.

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