Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert

Assertion A: Hydrolysis of an alkyl chloride is a slow reaction but in the presence of NaI, the rate of hydrolysis increases.

Reason R: I- is a good nucleophile as well as a good leaving group.

In the light of the above statements, choose the correct answer from the options given below.

ChemistryHaloalkanes and HaloarenesJEE MainJEE Main 2023 (24 Jan Shift 1)
Options:
  • A A is false but R is true
  • B A is true but R is false
  • C Both A and R are true and R is the correct explanation of A
  • D Both A and R are true and R is not the correct explanation of A
Solution:
2449 Upvotes Verified Answer
The correct answer is: Both A and R are true and R is the correct explanation of A

Iodide ion is a powerful nucleophile and hence reacts rapidly with RCl to form RI. Further because I ion is a better leaving group than Cl ion, therefore , RI is more rapidly hydrolysed than RCl to form ROH.

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.