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Question: Answered & Verified by Expert
Assertion $(\mathrm{A})\left[\mathrm{SiF}_6\right]^{2-}$ is formed but $\left[\mathrm{SiCl}_6\right]^{2-}$ is not
Reason (R) Electronegativity (EN) of $\mathrm{F}$ is higher than $\mathrm{EN}$ of $\mathrm{Cl}$
Chemistryp Block Elements (Group 13 & 14)AP EAMCETAP EAMCET 2018 (22 Apr Shift 1)
Options:
  • A Both (A) and (R) are correct and (R) is the correct explanation of (A)
  • B Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  • C (A) is correct but (R) is not correct
  • D (A) is not correct but (R) is correct
Solution:
1428 Upvotes Verified Answer
The correct answer is: Both (A) and (R) are correct but (R) is not the correct explanation of (A)
$\mathrm{SiF}_6^{2-}$ is formed but $\mathrm{SiCl}_6^{2-}$ is not because $\mathrm{Cl}$ has greater size than $\mathrm{F}$. Therefore, larger size of anions cannot form complex with silicon.
Electronegativity of $\mathrm{F}$ is higher than $\mathrm{Cl}$ but cannot explain about Assertion.
Thus, Assertion and Reason both are correct but Reason (R) is not the correct explanation of (A).

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