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Question: Answered & Verified by Expert
Assertion : Bond energy and bond dissociation energy have identical value for diatomic molecules.
Reason : Greater the bond dissociation energy, less reactive is the bond.
ChemistryThermodynamics (C)AIIMSAIIMS 2010
Options:
  • A If both assertion and reason are true and reason is the correct explanation of assertion
  • B If both assertion and reason are true but reason is not the correct explanation of assertion
  • C If assertion is true but reason is false
  • D If both assertion and reason are false.
Solution:
2887 Upvotes Verified Answer
The correct answer is: If both assertion and reason are true but reason is not the correct explanation of assertion
Bond dissociation energy is the energy required to break a particular bond in one mole of a gaseous molecule. Bond energy is the average values of dissociation energies of the same type of bond present in the molecule. Bond energy of $\mathrm{C}-\mathrm{H}$ bond in methane is $99.2 \mathrm{kcal} / \mathrm{mol}$. Thus for polyatomic molecules, average bond energy is taken as the dissociation bond energy.

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