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Question: Answered & Verified by Expert
Assertion : Conductivity of silicon increases by doping it with group-15 elements.
Reason : Doping means introduction of small amount of impurities like $\mathrm{P}, \mathrm{As}$ or Bi into the pure crystal.
Chemistryp Block Elements (Group 13 & 14)AIIMSAIIMS 2010
Options:
  • A If both assertion and reason are true and reason is the correct explanation of assertion
  • B If both assertion and reason are true but reason is not the correct explanation of assertion
  • C If assertion is true but reason is false
  • D If both assertion and reason are false.
Solution:
2577 Upvotes Verified Answer
The correct answer is: If both assertion and reason are true but reason is not the correct explanation of assertion
When a silicon crystal is doped with a group-15 elements, such as P, As, Sb or Bi the structure of the crystal lattice is left unchanged but an occasional atom with five valence electrons occupies a site that would normally be occupied by a silicon atom. The foreign atom uses four of its electrons in covalent bonding but the remaining fifth electron becomes delocalised and is thus free to contribute to electrical conduction.

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