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Question: Answered & Verified by Expert
Assertion : For Balmer series of hydrogen spectrum, the value $n_1=2$ and $n_2=3,4,5$.
Reason: The value of $n$ for a line in Balmer series of hydrogen spectrum having the highest wavelength is 4 and 6 .
ChemistryStructure of AtomAIIMSAIIMS 2002
Options:
  • A If both the assertion and reason are true and reason is a correct explanation of the assertion.
  • B If both assertion and reason are true but assertion is not a correct explanation of the assertion.
  • C If the assertion is true but the reason is false.
  • D If both assertion and reason are false.
Solution:
1925 Upvotes Verified Answer
The correct answer is: If the assertion is true but the reason is false.
The wavelength of the line can be calculated by the Ritz formula :
$$
\frac{1}{\lambda}=R\left(\frac{1}{n_1^2}-\frac{1}{n_2{ }^2}\right), R=\text { Rydberg constant }
$$
Therefore, for calculating highest wavelength in Balmer series $\left(n_1=2\right), n_2$ should be 3 .

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