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Assertion : Rate of hydrolysis of methyl chloride to methanol is higher in DMF than in water.
Reason : Hydrolysis of methyl chloride follows second order kinetics.
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Reason : Hydrolysis of methyl chloride follows second order kinetics.
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If both assertion and reason are true and reason is the correct explanation of assertion
Hydrolysis of methyl chloride to methanol follows $\mathrm{S}_{\mathrm{N}} 2$ reaction. The rates of many $\mathrm{S}_{\mathrm{N}} 2$ reactions are affected by the solvent. Protic solvents - those that contain $-\mathrm{OH}$ or $-\mathrm{NH}$ group are generally the worst solvents for $\mathrm{S}_{\mathrm{N}}$. Polar protic solvents, (like water, alcohols and carboxylic acids), which have strong dipoles but don't have $-\mathrm{OH}$ or $-\mathrm{NH}$ groups are the best. In contrast to protic solvents, which decrease the rates of $\mathrm{S}_{\mathrm{N}} 2$ reactants by lowering the ground state energy of nucleophile, polar aprotic solvents (DMF) increase the rates of $\mathrm{S}_{\mathrm{N}} 2$ reactions by raising the ground state energy of nucleophile.
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