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Question: Answered & Verified by Expert
Assertion : The presence of nitro group facilitates nucleophilic substitution reactions in aryl halides.
Reason : The intermediate carbanion is stabilised due to the presence of nitro group.
ChemistryHaloalkanes and HaloarenesAIIMSAIIMS 2006
Options:
  • A If both assertion and reason are true and reason is the correct explanation of the assertion
  • B If both assertion and reason are true but reason is not the correct explanation of the assertion
  • C If assertion is true, but reason is false
  • D Both assertion and reason are false statements.
Solution:
1762 Upvotes Verified Answer
The correct answer is: If both assertion and reason are true and reason is the correct explanation of the assertion
The $\mathrm{C}$-atom of $\mathrm{C}-\mathrm{Cl}$ in chloronitrobenzene carries a small +ve charge.


Because of the positive charge, attack at this carbon atom by the nucleophile is facilitated.

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