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Question: Answered & Verified by Expert
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bar at the same temperature, what would be its concentration?
[Report your answer upto two decimal places.]
ChemistrySolutionsJEE Main
Solution:
2877 Upvotes Verified Answer
The correct answer is: 0.06
π = CRT = W B × R × T M B × V

For both solutions, R, T and V are constants.

For I solution

4.98 bar = 36g × R × T 180 g mol - 1 × V ...(i)

For II solution

1.52 bar = W B × R × T M B × V ...(ii)

On dividing Eq. (ii) by Eq. (i), we get

1.52 bar 4.98 bar = W B × R × T M B × V × 180 × V 36 × R × T

W B M B = 1.52 4.98 × 5 = 0.0610 mol L - 1

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