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Question: Answered & Verified by Expert
At  80C , the vapour pressure of pure liquid 'A' is 520mmHg and that of pure liquid 'B' is 1000mmHg. If a mixture solution of 'A' and 'B' boils at 80C and 1 atm pressure, the amount of 'A' in the mixture is:
( 1atm=760mmHg )
ChemistrySolutionsNEET
Options:
  • A 52 mole percent
  • B 34 mole percent
  • C 48 mole percent
  • D 50 mole percent
Solution:
1165 Upvotes Verified Answer
The correct answer is: 50 mole percent
PT = PAXA+PBXB

Mixture solution boil at 1 atm = 760 mm Hg = total pressure of solution.

7 6 0 = 520X A + 1 0 00 1 - X A

7 6 0 = 5 2 0 X A + 1 0 0 0 - 1 0 0 0 X A 4 8 0 X A = 2 4 0

X A =0.5,

mole percentage of A=50%

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