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Question: Answered & Verified by Expert
Atomic number of Hydrogen like species that has a wave length difference of 59.3 nm between first line of Balmer and first line of Lyman series is (R H =109678 cm 1 )
ChemistryStructure of AtomJEE Main
Solution:
2074 Upvotes Verified Answer
The correct answer is: 3
Wavelength of 1st line in Balmer series,
1 λ B = Z 2 R H 1 2 2 1 3 2 = 5 36 R H Z 2
or λ B = 36 5 R H Z 2
Wavelength of 1st line in Lyman series is, 1 λ L = Z 2 R H 1 1 2 1 2 2
or λ L = 4 3× R H Z 2
Difference λ B λ L =59.3× 10 7 = 36 5 R H Z 2 4 3 R H Z 2
= 1 R H Z 2 36 5 4 3
Z 2 = 88 59.3× 10 7 ×109678×15 =9.0
or Z=3
Hydrogen-like species is Li 2+

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