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Question: Answered & Verified by Expert
Benzene diazonium chloride in aqueous solution decomposes as :
C 6 H 5 - N = N + Cl aq - + H 2 O aq C 6 H 5 OH aq + N 2 g + HCl (aq)
The reaction follows first order kinetics. If pt is the pressure of N2 at constant volume and temperature corresponding to different intervals of time t and pf that after completion of the reaction, then which of the following graphs conforms to the kinetics of the reaction ?
ChemistryChemical KineticsNEET
Options:
  • A
  • B
  • C
  • D
Solution:
2242 Upvotes Verified Answer
The correct answer is:
p f Initial moles of  C 6 H 5 N 2 + Cl - a p t Moles of  N 2  evolved at time t Moles of  C 6 H N 2 + Cl -   reacted

p f - p t  mole of  C 6 H 5 N 2 + Cl -  left at time t (a - x)

kt = 2 . 3 0 log  a a - x

kt= 2 . 3 0 log  p f p f - p t

kt 2.303 =log P f log P f P t

log p f - p t = log  p f - k 2 . 3 0 3 t

Interception y axis = log pf

Slope = - k 2 . 3 0 3

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