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Question: Answered & Verified by Expert
Bond enthalpies of \( \mathrm{A}_{2}, \mathrm{~B}_{2} \) and \( \mathrm{AB} \) are in the ratio \( 2: 1: 2 \). If bond enthalpy of formation of \( \mathrm{AB} \) is \( -100 \mathrm{KJ} \mathrm{mol}^{-1} \). The bond enthalpy of \( \mathrm{B}_{2} \) is
ChemistryThermodynamics (C)JEE Main
Options:
  • A \( 100 \mathrm{KJmol}^{-1} \)
  • B \( 50 \mathrm{KJmol}^{-1} \)
  • C \( 200 \mathrm{KJmol}^{-1} \)
  • D \( 150 \mathrm{KJmol}^{-1} \)
Solution:
1243 Upvotes Verified Answer
The correct answer is: \( 200 \mathrm{KJmol}^{-1} \)

Assume bond strength of A2=2X, then,

B2=X, AB=2X

ΔrHΘ=ΔdissHΘ-(R)ΔdissHΘ(P)

12 A2+12 B2AB

X+X2 - 2X = -100 kJ mol-1X = 200 kJ mol-1

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