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Question: Answered & Verified by Expert
Boron compounds behave as Lewis acid because of their
Chemistryp Block Elements (Group 13 & 14)AP EAMCETAP EAMCET 2021 (25 Aug Shift 1)
Options:
  • A electron rich in nature
  • B electron deficient in nature
  • C ionisation properties
  • D proton donating nature
Solution:
2752 Upvotes Verified Answer
The correct answer is: electron deficient in nature
Boron compounds are often employed as Lewis acids due to strong electrophilic nature granted by a vacant $p$-orbital into which electrons can be received. It behaves as Lewis acid as its number of valence shell electrons is 3 . Thus, its octet is incomplete.
e.g. $\mathrm{B}_2 \mathrm{H}_6$ (electron deficient compounds)
$$
\mathrm{B}(Z=5)=[\mathrm{He}] 2 s^2 2 p^1
$$
$\Rightarrow$ Total 5 electrons (incomplete octet)

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