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Question: Answered & Verified by Expert
Calculate the edge length of unit cell of metal which crystallises to bcc structure.
(Radius of metal atom $=173 \mathrm{pm}$ )
ChemistrySolid StateMHT CETMHT CET 2023 (10 May Shift 1)
Options:
  • A $5.01 \times 10^{-8} \mathrm{~cm}$
  • B $4.00 \times 10^{-8} \mathrm{~cm}$
  • C $4.5 \times 10^{-8} \mathrm{~cm}$
  • D $5.5 \times 10^{-8} \mathrm{~cm}$
Solution:
2715 Upvotes Verified Answer
The correct answer is: $4.00 \times 10^{-8} \mathrm{~cm}$
For bcc unit cell, $r=\frac{\sqrt{3}}{4} \mathrm{a}$
$\begin{aligned}
\therefore \quad \mathrm{a}=\frac{4 \mathrm{r}}{\sqrt{3}}=\frac{4 \times 173}{1.73} & =400 \mathrm{pm} \\
& =400 \times 10^{-10} \mathrm{~cm} \\
& =4.00 \times 10^{-8} \mathrm{~cm}
\end{aligned}$

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