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Question: Answered & Verified by Expert
Calculate the solubility product of Co2[Fe(CN)6] in water at 25° C.
Given, conductivity of saturated solutions of Co2[Fe(CN)6] is 2.06× 10 6 Ω 1 cm 1 and that of water used is 4.1× 10 7 Ω 1 cm 1 . The ionic molar conductivities of Co2+ and [Fe(CN)6]4- are 86.0Ω cm 2 mol 1 and 444.0 Ω 1 cm 2 mol 1 , respectively.
ChemistryIonic EquilibriumJEE Main
Options:
  • A 7.87× 10 17
  • B 7.87×10-6
  • C 7.87×10-8
  • D 7.87×10-9
Solution:
2607 Upvotes Verified Answer
The correct answer is: 7.87× 10 17
κCo2[Fe(CN)6]=2.06×10-6-0.41×10-6=1.65×10-6
ΛmCo2[Fe(CN)6]=2ΛmCo2++Λm[Fe(CN)6]4-
=2×86+444=616 Scm 2 mol 1
Λm=1000κc
c=2.7×10-6M
KspCo2[Fe(CN)6]=4c3=7.87×10-17M3.

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