Search any question & find its solution
Question:
Answered & Verified by Expert
Calculate the standard cell potentials of galvanic cell in which the following reactions take place \( 2 \mathrm{Cr}(\mathrm{s})+3 \mathrm{Cd}^{2+}(\mathrm{aq}) \longrightarrow 2 \mathrm{Cr}^{3+}(\mathrm{aq})+3 \mathrm{Cd} \) Calculate the \( \Delta_{\mathrm{r}} \mathrm{G}^{0} \) and equilibrium constant for the reactions. \(\mathrm{E}_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^{\mathrm{o}}=-0.74 \mathrm{~V}, \mathrm{E}_{\mathrm{Cd}^{2+} / \mathrm{Cd}}^{\mathrm{o}}=-0.40 \mathrm{~V}\) The values of \( E_{\text {cell }}^{0}, \Delta_{r} G^{0} \) and \( \mathrm{K}_{\mathrm{C}} \) may be
Options:
Solution:
2906 Upvotes
Verified Answer
The correct answer is:
\( \begin{array}{ccc}E_{\text {cell }}^{0} & \Delta_{r} G^{0} & K_{c} \\ 0 \cdot 34 \mathrm{~V} & -196 \cdot 86 \mathrm{~kJ} & 3 \cdot 17 \times 10^{34}\end{array} \)
Given ;
(a) Calculation of standard cell potential (Eo)
(b) Calculation of .
We know that ,
Here the value of n = 6
thus ,
(c) Calculation of equilibrium constant (Kc)
Looking for more such questions to practice?
Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.