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Question: Answered & Verified by Expert
Calculate the work done when 112 g iron reacts with dilute HCl at 300 K. The reaction is carried out in an open container

(At mass of Fe = 56)
ChemistryThermodynamics (C)JEE Main
Options:
  • A 600 cal
  • B 300 cal
  • C 200 cal
  • D 1200 cal
Solution:
2464 Upvotes Verified Answer
The correct answer is: 1200 cal
The number of moles of Fe taken

=11256=2

So the chemical reaction is

2Fes+4HClaq2FeCl2aq+2H2g

New work done =PV2-V1

Since V2-V1=VH2

Hence volume of solids and liquids is taken as 0

So work done =P.VH2

also PVH2=nRT or VH2=nRTP

So work done =P.nRTP=nRT [ R=2 Cal]

=2×2×300=1200 Cal.

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