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Question: Answered & Verified by Expert
Calculate value of E°Ce4+/Ce3+ . If E°cell for the cell reaction, 2Ce4++Co2Ce3++Co2+ is 1.89 V. If E°Co/Co2+ = -0.28 V
ChemistryElectrochemistryJEE Main
Options:
  • A  1.64V
  • B + 1.64V
  • C  2.08V
  • D + 2.17V
Solution:
2416 Upvotes Verified Answer
The correct answer is: + 1.64V
In this cell Co is oxidised and it acts as anode and Ce acts as cathode.

ECell0=ECathode0-EAnode0=1.89=ECell0-(-0.28)

ECell0=1.89-0.28=1.61 Volts.

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