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Question: Answered & Verified by Expert
Carbon can reduce ferric oxide to iron at a temperature above $983 \mathrm{~K}$ because
ChemistryGeneral Principles and Processes of Isolation of MetalsKCETKCET 2010
Options:
  • A carbon monoxide formed is thermodynamically less stable than ferric oxide
  • B carbon has a higher affinity towards oxidation than iron
  • C free energy change for the formation of carbon dioxide is less negative than that for ferric oxide
  • D iron has a higher affinity towards oxygen than carbon
Solution:
2162 Upvotes Verified Answer
The correct answer is: carbon has a higher affinity towards oxidation than iron
Above $983 \mathrm{~K}$, free energy change for the formation of $\mathrm{CO}_{2}$ is more negative than that for ferric oxide. Thus, above this temperature, carbon has a higher affinity towards oxidation than iron.

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