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Question: Answered & Verified by Expert
Carbon cannot reduce $\mathrm{Fe}_{2} \mathrm{O}_{3}$ to $\mathrm{Fe}$ at a temperature below $983 \mathrm{~K}$ because
ChemistryGeneral Principles and Processes of Isolation of MetalsKCETKCET 2011
Options:
  • A free energy change for the formation of $\mathrm{CO}$ is more negative than that of $\mathrm{Fe}_{2} \mathrm{O}_{3}$
  • B $\mathrm{CO}$ is thermodynamically more stable than $\mathrm{Fe}_{2} \mathrm{O}_{3}$
  • C carbon has higher affinity towards oxygen than iron
  • D iron has higher affinity towards oxygen than carbon
Solution:
1257 Upvotes Verified Answer
The correct answer is: iron has higher affinity towards oxygen than carbon



Below $983 \mathrm{~K}$, conversion of iron to ferric oxide is more favourable.

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