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Catalytic dehydrogenation of $n$-haptane in presence of $\mathrm{Cr}_2 \mathrm{O}_3 / \mathrm{Al}_2 \mathrm{O}_3$ at $750 \mathrm{~K}$ gives
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1-heptene
Octane number is related to the percentage of iso-octane since iso-octane is $81 \%$ hence octane number is $81 \%$.


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