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Question: Answered & Verified by Expert
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in group 14 elements follows the order
Chemistryp Block Elements (Group 13 & 14)
Options:
  • A
    $\mathrm{C}>\mathrm{Si}>\mathrm{Ge}>\mathrm{Sn}$
  • B
    $\mathrm{C}>>\mathrm{Si}>\mathrm{Ge} \approx \mathrm{Sn}$
  • C
    Si $>\mathrm{C}>\mathrm{Sn}>\mathrm{Ge}$
  • D
    $\mathrm{Ge}>\mathrm{Sn}>\mathrm{Si}>\mathrm{C}$
Solution:
1380 Upvotes Verified Answer
The correct answer is:
$\mathrm{C}>>\mathrm{Si}>\mathrm{Ge} \approx \mathrm{Sn}$
The tendency of forming long open or closed chains by combination of some atoms in themselves is known as catenation. The tendency of catenation is maximum in carbon and decreases on moving down the group.
$$
\mathrm{C}>>\mathrm{Si}>\mathrm{Ge} \approx \mathrm{Sn}>\mathrm{Pb}
$$

This is due to high bond energy of $\mathrm{C}-\mathrm{C}$ bonds. On moving down the group, atomic size increases and electronegativity decreases, hence, tendency to show catenation decreases.

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