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Question: Answered & Verified by Expert
$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH} \underset{\text { step-1 }}{\stackrel{\mathrm{Cl}_2}{\longrightarrow}} \mathrm{CH}_3 \mathrm{CHO}$ $\underset{\text { step-2 }}{\stackrel{3 \mathrm{Cl}_2}{\longrightarrow}} \mathrm{Cl}_3 \mathrm{CCHO}$
In above reactions the role of $\mathrm{Cl}_2$ in step- 1 and step-2 respectively is :
ChemistryAlcohols Phenols and EthersAP EAMCETAP EAMCET 2006
Options:
  • A oxidation, chlorination
  • B reduction, chlorination
  • C oxidation, addition
  • D reduction, substitution
Solution:
2992 Upvotes Verified Answer
The correct answer is: oxidation, chlorination
$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH} \underset{\text { Step 1 }}{\stackrel{\mathrm{Cl}_2}{\longrightarrow}} \mathrm{CH}_3 \mathrm{CHO}$
The above reaction is an example of oxidation. Due to oxidation $-\mathrm{CH}_2 \mathrm{OH}$ group is oxidised to -CHO group.
$\mathrm{CH}_3 \mathrm{CHO} \underset{\text { Step } 2}{\stackrel{3 \mathrm{Cl}_2}{\longrightarrow}} \mathrm{Cl}_3 \cdot \mathrm{C} \cdot \mathrm{CHO}$
In the second step chlorination takes place. In chlorination hydrogen atom changes by chlorine.

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