Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert
Choose the correct order of stability of carbocation using the concept of hyperconjugation.

ChemistryGeneral Organic ChemistryJEE Main
Options:
  • A \( \mathrm{I} < \mathrm{II} < \mathrm{III} < \mathrm{IV} \)
  • B \( \mathrm{IV} < \mathrm{III} < \mathrm{II} < \mathrm{I} \)
  • C \( \mathrm{III} < \mathrm{IV} < \mathrm{II} < \mathrm{I} \)
  • D None of the above
Solution:
1548 Upvotes Verified Answer
The correct answer is: \( \mathrm{IV} < \mathrm{III} < \mathrm{II} < \mathrm{I} \)

Greater the number of alkyl groups attached to a positively charged carbon atom, the greater is the hyper conjugation interaction and stabilisation of the cation. Thus, we have the following relative stability of carbocation:

               (CH3)3C+                       >             (CH3)2CH+                    >               CH3CH2+                        >      CH3+        9 hyperconjugative structure             6 hyperconjugative structure        3 hyperconjugative structure 

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.