Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert
Choose the correct statement. $\mathrm{Fe}^{3+}$ ion is more stable than $\mathrm{Fe}^{2+}$ ion because
Chemistryd and f Block ElementsTS EAMCETTS EAMCET 2022 (20 Jul Shift 2)
Options:
  • A More the charge on the atom, more is its stability
  • B Configuration of $\mathrm{Fe}^{2+}$ is $3 \mathrm{~d}^6$ while $\mathrm{Fe}^{3+}$ is $3 \mathrm{~d}^5$
  • C $\mathrm{Fe}^{2+}$ has a larger size than that of $\mathrm{Fe}^{3+}$
  • D $\mathrm{Fe}^{3+}$ ions are coloured
Solution:
1708 Upvotes Verified Answer
The correct answer is: Configuration of $\mathrm{Fe}^{2+}$ is $3 \mathrm{~d}^6$ while $\mathrm{Fe}^{3+}$ is $3 \mathrm{~d}^5$
In $\mathrm{Fe}^{3+}$, the d-orbital is half-filled $\left(\mathrm{d}^5\right)$. So, it has the maximum exchange energy which, in turn, leads to extra stability over $\mathrm{Fe}^{2+}\left(\mathrm{d}^6\right)$.

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.