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Question: Answered & Verified by Expert
Chromyl chloride converts methyl group to a chromium complex, which on acid hydrolysis gives corresponding aldehyde. This reaction is called
ChemistryAldehydes and KetonesMHT CETMHT CET 2020 (14 Oct Shift 2)
Options:
  • A Stephen reaction
  • B Wolff-Kishner reaction
  • C Etard reaction
  • D Rosenmund reaction
Solution:
1128 Upvotes Verified Answer
The correct answer is: Etard reaction
When toluene is treated with solution of chromyl chloride $\left(\mathrm{CrO}_{2} \mathrm{Cl}_{2}\right)$ in $\mathrm{CS}_{2}$, brown chrominum complex is obtained, which on acid hydrolysis gives benzaldehyde. This reaction is called Etard reaction.

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