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Cobalt chloride when dissolved in water forms pink colored complex which has octahedral geometry. This solution on treating with cone forms deep blue complex, which has a geometry. and , respectively, are
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Cobalt chloride when dissolved in water forms pink coloured is . This is due to the electronic transition of an electron from to energy level of complex. When excess of is added to the solution is transformed into deep blue colour complex .
Tetrahedral complexes have smaller crystal field splitting than octahedral complexes.
Hence,
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