Concentrated H 2 SO 4 reacts with PCl 5 to produce, HClO 2 , SO 2 Cl 2 , SOCl 2 , HClO 4

When excess of Pa 5 reacts with conc. H 2 SO 4 , it gives suphuryl chloride ( SO 2 Cl 2 ) as product

Concentrated H 2 SO 4 reacts with PCl 5 to produce

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Concentrated $\mathrm{H}_{2} \mathrm{SO}_{4}$ reacts with $\mathrm{PCl}_{5}$ to produce

Chemistryp Block Elements (Group 15, 16, 17 & 18)MHT CETMHT CET 2020 (13 Oct Shift 2)

Options:

A $\mathrm{HClO}_{2}$
B $\mathrm{SO}_{2} \mathrm{Cl}_{2}$
C $\mathrm{SOCl}_{2}$
D $\mathrm{HClO}_{4}$

Solution:

1299 Upvotes Verified Answer

The correct answer is: $\mathrm{SO}_{2} \mathrm{Cl}_{2}$

When excess of $\mathrm{Pa}_{5}$ reacts with conc. $\mathrm{H}_{2} \mathrm{SO}_{4}$, it gives suphuryl chloride $\left(\mathrm{SO}_{2} \mathrm{Cl}_{2}\right)$ as product

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