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Question: Answered & Verified by Expert
Consider the decomposition of N2O5 as
N2O52NO2+12O2
The rate of reaction is given by
-d[N2O5]dt=12d[NO2]dt=2d[O2]dt=k1[N2O5]
Therefore, -d[N2O5]dt=k1[N2O5]
+d[NO2]dt=2k1[N2O5]=k1'[N2O5]
d[O2]dt=12k1[N2O5]=k1"[N2O5]
Choose the correct option.
ChemistryChemical KineticsNEET
Options:
  • A 4k1=2k1'=k1"
  • B 4k1=k1'=2k1"
  • C k1=2k1'=k1"
  • D 2k1=k1'=4k1"
Solution:
1500 Upvotes Verified Answer
The correct answer is: 2k1=k1'=4k1"
-d[N2O5]dt=12d[NO2]dt=2d[O2]dt
k1[N2O5]=12k1'[N2O5]=2×k1"[N2O5]
k1=12k1'=2k1"
=2k1=k1'=4k1"

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