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Question: Answered & Verified by Expert
Consider the following bromides :


The correct order of $\mathrm{S}_{\mathrm{N}} 1$ reactivity is
ChemistryHaloalkanes and HaloarenesJEE MainJEE Main 2010
Options:
  • A
    $B>C>A$
  • B
    $B>A>C$
  • C
    $C>B>A$
  • D
    $A>B>C$
Solution:
1401 Upvotes Verified Answer
The correct answer is:
$B>C>A$
$\mathrm{S}_{\mathrm{N}} 1$ proceeds via carbocation intermediate, the most stable one forming the product faster. Hence reactivity order for $\mathrm{A}, \mathrm{B}, \mathrm{C}$ depends on stability of carbocation created.

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