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Consider the following statements:
(I) is the least basic among hydroxides of lanthanides.
(II) and possess almost the same ionic radii.
(III) can act as an oxidizing agent.
Which of the above is/are true?
Options:
(I) is the least basic among hydroxides of lanthanides.
(II) and possess almost the same ionic radii.
(III) can act as an oxidizing agent.
Which of the above is/are true?
Solution:
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Verified Answer
The correct answer is:
and
The basic character of hydroxides decreases from to . Due to smaller size of the bond attains more covalent character.
Also, due to Lanthanide contraction and possess almost the same ionic radii.
is a strong oxidant.

Also, due to Lanthanide contraction and possess almost the same ionic radii.
is a strong oxidant.
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