Join the Most Relevant JEE Main 2025 Test Series & get 99+ percentile! Join Now
Search any question & find its solution
Question: Answered & Verified by Expert
If electrolysis of aqueous CuSO $_{4}$ solution is carried out using Cu-electrodes, the reaction taking place at the anode is
ChemistryElectrochemistryWBJEEWBJEE 2019
Options:
  • A $\mathrm{H}^{+}+\mathrm{e}^{-} \rightarrow \mathrm{H}$
  • B $\mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Cu}(\mathrm{s})$
  • C $\mathrm{SO}_{4}^{2-}(\mathrm{aq})-2 \mathrm{e}^{-} \rightarrow \mathrm{SO}_{4}$
  • D $\mathrm{Cu}(\mathrm{s})-2 e^{-} \rightarrow \mathrm{Cu}^{2+}(\mathrm{aq})$
Solution:
2921 Upvotes Verified Answer
The correct answer is: $\mathrm{Cu}(\mathrm{s})-2 e^{-} \rightarrow \mathrm{Cu}^{2+}(\mathrm{aq})$
Electrolysis of copper sulphate solution using Cu-electrodes,
Ions present : $\mathrm{Cu}^{2+}, \mathrm{H}^{+}, \mathrm{SO}_{4}^{2-}, \mathrm{OH}^{-}$
At cathode $\mathrm{Cu}^{2+}(a q)+2 e^{-} \rightarrow \mathrm{Cu}(s)$
At anode $\mathrm{Cu}(s)-2 e^{-} \rightarrow \mathrm{Cu}^{2+}(a q)$
So, the option (d) is correct answer.

Looking for more such questions to practice?

Download the MARKS App - The ultimate prep app for IIT JEE & NEET with chapter-wise PYQs, revision notes, formula sheets, custom tests & much more.