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Question: Answered & Verified by Expert
If enthalpy of hydrogenation of C 6 H 6 l into C 6 H 12 l is 205 kJ and resonance energy of C 6 H 6 l is 152 kJ mol1 then enthalpy of hydrogenation of  l to C 6 H 12 l is?
[Assume enthalpiies of vapourisation of all liquids involved are equal].
ChemistryThermodynamics (C)JEE Main
Options:
  • A – 535.5 kJ/mol
  • B – 238 kJ/mol
  • C – 357 kJ/mol
  • D – 119 kJ/mol
Solution:
1562 Upvotes Verified Answer
The correct answer is: – 119 kJ/mol
C 6 H 6 l + 3 H 2 g C 6 H 1 2 l
Δ H hyd C 6 H 6 l = - 2 0 5  kJ
Benzene on reactant side so add resonance energy of benzene with sign. Heat evolved for hydrogenation of three double bonds
=205152=357 kJ mol 1
Δ H hyd = - 3 5 7 3 = - 1 1 9  kJ / mole

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