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Question: Answered & Verified by Expert
If, the binding energy of electrons in a metal is \(250 \mathrm{~kJ} / \mathrm{mol}\), what should be the threshold frequency of the striking photons in order to free an electron from the metal surface?
ChemistryStructure of AtomAP EAMCETAP EAMCET 2020 (21 Sep Shift 1)
Options:
  • A \(6.26 \times 10^{14} \mathrm{~s}^{-1}\)
  • B \(12.4 \times 10^{14} \mathrm{~s}^{-1}\)
  • C \(6.26 \times 10^{12} \mathrm{~s}^{-1}\)
  • D \(12.4 \times 10^{12} \mathrm{~s}^{-1}\)
Solution:
2608 Upvotes Verified Answer
The correct answer is: \(6.26 \times 10^{14} \mathrm{~s}^{-1}\)
Binding energy of 1 mole of electrons \(=250 \mathrm{~kJ}\) Binding energy of 1 electron
\(\begin{aligned}
& =(250) /\left(6.022 \times 10^{23}\right) \mathrm{kJ} \\
& =4.15 \times 10^{-22} \mathrm{~kJ} \\
& =4.15 \times 10^{-19} \mathrm{~J}
\end{aligned}\)
Threshold energy \(\left(h v_0\right)=\) Binding energy
\(\begin{aligned}
\therefore h v_0 & =4.15 \times 10^{-19} \mathrm{~J} \\
\text {or } v_0 & =\left(4.15 \times 10^{-19} \mathrm{~J}\right) / h \\
& =\left(4.15 \times 10^{19} \mathrm{~J}\right)\left(6.626 \times 10^{-34} \mathrm{~J} \mathrm{~s}\right) \\
& =6.26 \times 10^{14} \mathrm{~s}^{-1}
\end{aligned}\)
Hence, the correct option is (a).

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