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Question: Answered & Verified by Expert
If the degree of association is $70 \%$ for the reaction $2 A \rightleftharpoons(A)_2$ the van't-Hoff factor for the solute $A$ is
ChemistrySolutionsTS EAMCETTS EAMCET 2018 (07 May Shift 1)
Options:
  • A 0.30
  • B 0.70
  • C 0.35
  • D 0.65
Solution:
1621 Upvotes Verified Answer
The correct answer is: 0.65
$2 A \rightleftharpoons(A)_2$
van't-Hoff factor $(i)$
$70 \%=0.7$ per unit, i.e.
$\alpha=0.70$ (Given),
where, $\alpha=$ degree of association
$n=$ number of units undergo for association

$$
\begin{aligned}
& i=(1-\alpha)+\frac{\alpha}{n} \Rightarrow(1-0.70)+\frac{0.70}{2} \\
& i=0.30+0.35 \Rightarrow 0.65
\end{aligned}
$$

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