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Question: Answered & Verified by Expert
If the position of the electron is measured within an accuracy of \(\pm 0.002 \mathrm{~nm}\), calculate the uncertainty in the momentum of the electron. Suppose the momentum of the electron is \(h / 4 \pi \mathrm{m} \times 0.05 \mathrm{~nm}\), is there any problem in defining this value.
ChemistryStructure of Atom
Solution:
2256 Upvotes Verified Answer
\(\Delta x=0.002 \mathrm{~nm}=2 \times 10^{-3} \mathrm{~nm}=2 \times 10^{-12} \mathrm{~m}\)
\(\begin{aligned}
\Delta x \times \Delta p &=\frac{\mathrm{h}}{4 \pi} \\
\therefore \Delta p &=\frac{\mathrm{h}}{4 \pi \Delta x}=\frac{6.626 \times 10^{-34} \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-1}}{4 \times 3.14 \times\left(2 \times 10^{-12} \mathrm{~m}\right)} \\
&=2.638 \times 10^{-23} \mathrm{~kg} \mathrm{~ms}^{-1}
\end{aligned}\)
Actual momentum
\(\begin{aligned}
&=\frac{\mathrm{h}}{4 \pi \times 0.05 \mathrm{~nm}}=\frac{\mathrm{h}}{4 \pi \times 5 \times 10^{-11} \mathrm{~m}} \\
&=\frac{6.626 \times 10^{-34} \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-1}}{4 \times 3.14 \times 5 \times 10^{-11} \mathrm{~m}} \\
&=1.055 \times 10^{-24} \mathrm{~kg} \mathrm{~ms}^{-1}
\end{aligned}\)
This value cannot be defined as the actual magnitude of the momentum is smaller than the uncertainty in momentum, which is impossible.

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