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Question: Answered & Verified by Expert
If the radius of first orbit of $\mathrm{H}$ atom is $a_0$, the deBroglie wavelength of an electron in the third orbit is
ChemistryStructure of AtomJEE MainJEE Main 2012 (12 May Online)
Options:
  • A
    $4 \pi a_0$
  • B
    $8 \pi a_0$
  • C
    $6 \pi a_0$
  • D
    $2 \pi a_0$
Solution:
2380 Upvotes Verified Answer
The correct answer is:
$6 \pi a_0$
$r_n=a_0 n^2$
$$
\begin{aligned}
& r=a_0 \times(3)^2=9 a_0 \\
& m v r=\frac{n h}{2 \pi} \\
& m v=\frac{n h}{2 \pi \mathrm{r}}=\frac{3 h}{2 \pi \times 9 a_0}=\frac{h}{6 \pi a_0} \\
& \lambda=\frac{h}{m v}=\frac{h}{h} \times 6 \pi a_0=6 \pi a_0
\end{aligned}
$$

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