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Question: Answered & Verified by Expert
If uncertainty in position and momentum are equal, then uncertainty in velocity is
ChemistryStructure of AtomNEETNEET 2008 (Screening)
Options:
  • A $\frac{1}{2 m} \sqrt{\frac{h}{\pi}}$
  • B $\sqrt{\frac{h}{2 \pi}}$
  • C $\frac{1}{m} \sqrt{\frac{h}{\pi}}$
  • D $\sqrt{\frac{h}{\pi}}$
Solution:
1097 Upvotes Verified Answer
The correct answer is: $\frac{1}{2 m} \sqrt{\frac{h}{\pi}}$
Key Idea: According to Heisenberg's uncertainty principle, it is impossible to determine simultaneously the position and momentum of a moving microscopic particle, ie,
$\begin{aligned}
& \Delta x \times \Delta p \geq \frac{h}{4 \pi} \\
& \because \Delta x \times \Delta p \geq \frac{h}{4 \pi}
\end{aligned}$
Here $\Delta x=\Delta p$ and $\Delta p=m \cdot \Delta v$
$\begin{aligned}
& \therefore \Delta v^2=\frac{h}{m^2 4 \pi} \\
& \text {or } \\
& \Delta v=\frac{1}{2 m} \sqrt{\frac{h}{\pi}}
\end{aligned}$
Note: The uncertainty principle in terms of energy and time is given as
$\Delta E \cdot \Delta t \geq \frac{h}{4 \pi}$

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