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Question: Answered & Verified by Expert
In a cell that utilizes the reaction
Zn(s)+ 2H + (aq) Zn 2+ (aq)+ H 2 (g)
addition of H2SO4 to cathode compartment,
ChemistryElectrochemistryJEE Main
Options:
  • A Lowers the E and shifts equilibrium to the left
  • B Lowers the E and shifts the equilibrium to the right
  • C Increases the E and shifts the equilibrium to the right
  • D Increases the E and shifts the equilibrium to the left
Solution:
1953 Upvotes Verified Answer
The correct answer is: Increases the E and shifts the equilibrium to the right
Zn(s)+ 2H + (aq) Zn 2+ (aq)+ H 2 (g)
E  cell = E  cell o 0.059 2  log  Zn 2+ × p H 2 H + 2
On adding H 2 SO 4 , the H + will increase therefore E  cell will also increase and the equilibrium will shift towards the right.

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