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Question: Answered & Verified by Expert
In a chemical reaction, A+2BK2C+D , the initial concentration of B was 1.5 times of the concentration of A , but the equilibrium concentrations of A and B were found to be equal. The equilibrium constant K for the chemical reaction is:
ChemistryChemical EquilibriumJEE MainJEE Main 2019 (12 Jan Shift 1)
Options:
  • A 1
  • B 4
  • C 14
  • D 16
Solution:
2569 Upvotes Verified Answer
The correct answer is: 4
A      +      2B             2C    +    D
Initial conc. of [A] = a , [B] = 1.5a , [C] = 0 and [D] = 0

At equilibrium [A] = (a - x) , [B] = 1.5(a - 2x) , [C] = 2x and [D] = x

At equilibrium a-x=1.5a-2x

0.5a=x

a=2x

kC=2x2xa-x1.5a-2x2=4x2.xxx2=4

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