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Question: Answered & Verified by Expert
In a compound, atoms of element $Y$ form $c c p$ lattice and those of element $X$ occupy $2 / 3^{\text {rd }}$ of tetrahedral voids. The formula of the compound will be
ChemistrySolid StateVITEEEVITEEE 2018
Options:
  • A $\mathrm{X}_{4} \mathrm{Y}_{3}$
  • B $\mathrm{X}_{2} \mathrm{Y}_{3}$
  • C $\mathrm{X}_{2} \mathrm{Y}$
  • D $\mathrm{X}_{3} \mathrm{Y}_{4}$
Solution:
1398 Upvotes Verified Answer
The correct answer is: $\mathrm{X}_{4} \mathrm{Y}_{3}$
From the given data, we have
Number of $Y$ atoms in a unit cell $=4$
Number of $\mathrm{X}$ atoms in a unit cell
$=8 \times \frac{2}{3}=\frac{16}{3}$
From the above we get the formula of the compound as $X_{16 / 3} Y_{4}$ or $X_{4} Y_{3}$

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