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In a reaction of aniline a coloured product $C$ was obtained.

$\ ext {The structure of } C \text { would be}$
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$\ ext {The structure of } C \text { would be}$
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Key Idea : $1^{\circ}$ amines form diazonium salts at low temperature and diazonium salts are weak electrophiles, so react with strongly activated ring. (takes $\mathrm{H}$ from benzene nucleus).

Note : The $-\mathrm{N}=\mathrm{N}-$ linkage is called -azo linkage, and the reactions in which azo or diazo compounds are formed, are called diazo coupling reactions.

Note : The $-\mathrm{N}=\mathrm{N}-$ linkage is called -azo linkage, and the reactions in which azo or diazo compounds are formed, are called diazo coupling reactions.
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