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In case of nitrogen, $\mathrm{NCl}_3$ is possible but not $\mathrm{NCl}_5$ while in case of phosphorous, $\mathrm{PCl}_3$ as well as $\mathrm{PCl}_5$ are possible. It is due to
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availability of vacant d orbitals in P but not in N
availability of vacant d orbitals in P but not in N
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