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Question: Answered & Verified by Expert
In face centred cubic arrangement of A and B atoms, A atoms are at the corners of the unit cell and B atoms at the face centres. One of the A atoms is missing from one corner in the unit cell. The simplest formula of the compound is 
ChemistrySolid StateNEET
Options:
  • A A7B3
  • B AB3
  • C A7B24
  • D A7/8B5
Solution:
1081 Upvotes Verified Answer
The correct answer is: A7B24
If one atom (A) is missing from one corner,

no. of atoms A in unit cell = 7 × 1 8 = 7 8

no. of atoms B in unit cell = 6 × 1 2 = 3

A : B = 7 8 :  3  so simplest formula is A7B24

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