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In hydrogen atom spectra, if the ratio of wavelengths corresponding to the first of Lyman series and the first line of Balmer series is $9 \alpha$, the value of $\alpha$ is
PhysicsAtomic PhysicsTS EAMCETTS EAMCET 2021 (06 Aug Shift 2)
Options:
  • A 0.5
  • B 0.8
  • C 0.6
  • D 0.021
Solution:
2433 Upvotes Verified Answer
The correct answer is: 0.021
According to Bohr, the wavelength emitted when an electron jumps from $n_1$ th to $n_2$ th orbit is given as
$\frac{1}{\lambda}=R\left(\frac{1}{n_1^2}-\frac{1}{n_2^2}\right)$
For first line of Lyman series, $n_1=1$ and $n_2=2$
$\begin{array}{llll}
& & \frac{1}{\lambda_1} & =R\left(\frac{1}{1^2}-\frac{1}{2^2}\right) \\
\therefore & \frac{1}{\lambda_1} & =R\left(1-\frac{1}{2^2}\right)=\frac{3 R}{4}
\end{array}$
For the first line of Balmer series, $n_1=2$ and $n_2=3$

$\therefore$ Dividing Eq. (ii) by Eq (i), we get
$\begin{array}{llll}
\frac{\lambda_1}{\lambda_2} =\frac{5 R}{36} \times \frac{4}{3 R} \\
\Rightarrow \quad \frac{5}{27} =9 \alpha \\
\Rightarrow \quad \alpha =\frac{5}{27 \times 9}=0.021
\end{array}$

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