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Question: Answered & Verified by Expert
In $\mathrm{KO}_2$, the nature of oxygen species and the oxidation state of oxygen atom are, respectively:
Chemistrys Block ElementsJEE MainJEE Main 2018 (15 Apr Shift 2 Online)
Options:
  • A
    Superoxide and $-1$
  • B
    Superoxide and $-1 / 2$
  • C
    Peroxide and $-1 / 2$
  • D
    Oxide and $-2$
Solution:
2920 Upvotes Verified Answer
The correct answer is:
Superoxide and $-1 / 2$
In $\mathrm{KO}_2$, the nature of oxygen species and the oxidation state of oxygen atom are superoxide (superoxide ion is $\mathrm{O}_2^{-}$) and $-1 / 2$ respectively.
Let $x$ be oxidation state of oxygen. The oxidation state of $\mathrm{K}$ is $+1$. Hence
$$
\begin{gathered}
+1+2(x)=0 \\
2 x=-1 \\
x=-\frac{1}{2}
\end{gathered}
$$

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