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Question: Answered & Verified by Expert
In $\mathrm{PO}_{4}^{3-},$ the formal charge on each oxygen atom and the $\mathrm{P}-\mathrm{O}$ bond order respectively are
ChemistryChemical Bonding and Molecular StructureJEE Main
Options:
  • A -0.75,0.6
  • B -0.75,1.0
  • C -0.75,1.25
  • D -3,1.25
Solution:
2300 Upvotes Verified Answer
The correct answer is: -0.75,1.25



Bond order

$=\frac{\text { Number of bonds }}{\text { Number of Resonating structures }}$

$=\frac{5}{4}=1.25$

Three unit negative charge is being shared by four $\mathrm{O}$ atoms. Formal charge $=-3 / 4$

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