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Question: Answered & Verified by Expert

In the above reaction, left hand side and right hand side rings are named as A and B respectively. They undergo ring expansion. The correct statement for this process is:

ChemistryAlcohols Phenols and EthersJEE MainJEE Main 2023 (13 Apr Shift 1)
Options:
  • A

    Ring expansion can go upto seven membered rings

  • B

    Finally both rings will become six membered each.

  • C

    Finally both rings will become five membered each.

  • D

    Only A will become 6 membered.

Solution:
2005 Upvotes Verified Answer
The correct answer is:

Finally both rings will become six membered each.

The reaction proceeds through a carbocation intermediate. The carbocation formed undergo rearrangement by ring expansion. Four membered ring undergo ring expansion to five membered ring and five membered ring undergo ring expansion to six membered ring and finally it converts to alkene by losing proton. 

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