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Question: Answered & Verified by Expert
In the extraction of Ca by electro reduction of molten $\mathrm{CaCl}_{2}$ some $\mathrm{CaF}_{2}$ is added to the electrolyte for the following reason:
Chemistrys Block ElementsWBJEEWBJEE 2020
Options:
  • A To keep the electrolyte in liquid state at temperature lower than the m. p. of $\mathrm{CaCl}_{2}$
  • B To effect precipitation of Ca
  • C To effect the electrolysis at lower voltage
  • D To increase the current efficiency
Solution:
1168 Upvotes Verified Answer
The correct answer is: To keep the electrolyte in liquid state at temperature lower than the m. p. of $\mathrm{CaCl}_{2}$
Hint:
$\mathrm{CaF}_{2}$ decreases the melting point of $\mathrm{CaCl}_{2}$

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